Organic Chemistry Some Basic Principles And Techniques Ques 60

60. Which one of the following is a technique most suitable for purification of cyclohexanone from a mixture containing benzoic acid, isoamyl alcohol, cyclohexane and cyclohexanone?

[1997]

(a) Crystallization

(b) Sublimation

(c) IR spectroscopy

(d) Gas chromatography

Show Answer

Answer:

Correct Answer: 60.(c)

Solution:

  1. (c) $IR$ spectroscopy is used for the purification of cyclohexanone from a mixture of benzoic acid, isoamyl alcohol, cyclohexane and cyclohexanone. Because in this method, each functional group appear at a certain peak. So, cyclohexanone can be identified by carbonyl peak.

An amyl alcohol is any one of $8$ alcohols with the formula $C_5 H _{12} O$ (alkanol with $5$ carbons).