Periodic Classification And Periodic Properties Ques 13

13. The first ionisation potential of $\mathrm{Na}, \mathrm{Mg}, \mathrm{Al}$ and $\mathrm{Si}$ are in the order

(a) $\mathrm{Na}<\mathrm{Mg}>\mathrm{Al}<\mathrm{Si}$

(b) $\mathrm{Na}>\mathrm{Mg}>\mathrm{Al}>\mathrm{Si}$

(c) $\mathrm{Na}<\mathrm{Mg}<\mathrm{Al}>\mathrm{Si}$

(d) $\mathrm{Na}>\mathrm{Mg}>\mathrm{Al}<\mathrm{Si}$

(1988, 1M)

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Answer:

Correct Answer: 13.(c)

Solution:

  1. Ionisation energy increases from left to right in a period. However, exception occur between group 2 and group 13 elements on account of stability of electronic configuration of valence shell.

$\Rightarrow$ The desired order is $\mathrm{Na}<\mathrm{Mg}>\mathrm{Al}<\mathrm{Si}$