Redox Reactions Ques 3

3. Phosphorus has the oxidation state of $+3$ in

[1994]

(a) Phosphorous acid

(b) Orthophosphoric acid

(c) Hypophosphorous acid

(d) Metaphosphoric acid.

Show Answer

Answer:

Correct Answer: 3.(a)

Solution:

  1. (a) $O.N.$ of $P$ in $H_3 PO_3$ (phosphorous acid)

$3 \times 1+x+3 \times(-2)=0$ or $x=+3$

In orthophosphoric acid $(H_3 PO_4)$ $O.N.$ of $P$ is $+5$ , in hypophosphorous acid $(H_3 PO_2)$ it is $+1$ while in metaphosphoric acid $(HPO_3)$, it is $+5$ .