Redox Reactions Ques 8

8. When $Cl_2$ gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from :

[2012]

(a) zero to $+1$ and zero to $-5$

(b) zero to $-1$ and zero to $+5$

(c) zero to $-1$ and zero to $+3$

(d) zero to $+1$ and zero to $-3$

Show Answer

Answer:

Correct Answer: 8.(b)

Solution:

  1. (b) On reaction with hot and concentrated alkali a mixture of chloride and chlorate is formed

$3 Cl_2+3 NaOH$ (excess) $\xrightarrow{\text{ Hot }}$ $5 NaCl+NaClO_3+3 H_2 O $