The D And F Block Elements Ques 28

28. The common oxidation states of Ti are [1994]

(a) $+2,+3$

(b) $+3,+4$

(c) $-3,-4$

(d) $+2,+3,+4$

Show Answer

Solution:

  1. (b) $Ti(22)=[Ar] 3 d^{2} 4 s^{2}$

minimum oxidation state is +2 and maximum oxidation state is +4 .

$Ti^{4+}=[Ar]$

Hence, it is most stable state of Ti.

$Ti^{3+}=[Ar] 3 d^{1}$

It acts as a good reducing agent as it can readily oxidized to $Ti^{4+}$ ion.

$Ti^{2+}=[Ar] 3 d^{2}$

It is the most unstable form.

Thus, +3 and +4 are the common oxidation states. $\frac{2}{\text{ 이 }}$

The minimum oxidation state of transition metals is equal to the number of electrons in $4 s$ shell and the maximum oxidation state is equal to the sum of the $4 s$ and $3 d$ electrons.



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