The D And F Block Elements Ques 4

4. Four successive members of the first series of the transition metals are listed below. For which one of them the standard potential $(E _{M^{2+} / M}^{\circ})$ value has a positive sign?

[2012 M]

(a) $Co(Z=27)$

(b) $Ni(Z=28)$

(c) $Cu(Z=29)$

(d) $Fe(Z=26)$

Show Answer

Solution:

(c) $E _{Cu^{+2} / Cu}^{\circ}=0.34$ volt,

Other has - ve $E _{\text{R.P. }}^{\circ}$

$E _{Co^{++} / Co}^{\circ}=-0.28$

$E _{Ni^{++} / Ni}^{\circ}=-0.25$

$E _{Fe^{+} / Fe}^{\circ}=-0.44$



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