The P Block Elements Ques 56

56. It is possible to obtain oxygen from air by fractional distillation because [1989]

(a) oxygen is in a different group of the periodic table from nitrogen

(b) oxygen is more reactive than nitrogen

(c) oxygen has higher b.p. than nitrogen

(d) oxygen has a lower density than nitrogen.

Show Answer

Solution:

  1. (c) Oxygen has higher b.pt. than nitrogen therefore it can be obtained from air by fractional distillation.

Air is liquified by making use of the joule-Thomson effect (cooling by expansion of the gas). Water vapour and $CO_2$ are removed by solidification. The remaining constituents of liquid air i.e., liquid oxygen and liquid nitrogen are separated by means of fractional distillation.



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