The Pblock Elements Ques 16

16. The straight chain polymer is formed by

[2009]

(a) hydrolysis of $CH_3 SiCl_3$ followed by condensation polymerisation

(b) hydrolysis of $(CH_3)_4 Si$ by addition polymerisation

(c) hydrolysis of $(CH_3)_2 SiCl_2$ followed by condensation polymerisation

(d) hydrolysis of $(CH_3)_3 SiCl$ followed by condensation polymerisation

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Answer:

Correct Answer: 16.(c)

Solution:

  1. (c) Hydrolysis of substituted chlorosilanes yield corresponding silanols which undergo polymerisation.

Polymerisation of dimethylsilanol yields linear thermoplastic polymer.