The Sblock Elements Ques 26

26. Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy?

[2010]

(a) $\mathrm{CaSO}_4$

(b) $\mathrm{BeSO}_4$

(c) $\mathrm{BaSO}_4$

(d) $\mathrm{SrSO}_4$

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Answer:

Correct Answer: 26.(b)

Solution: (b) $\mathrm{Be}^{2+}$ is very small, hence its hydration enthalpy is greater than its lattice enthalpy. Also, hydration energy decreases down the group.