The Sblock Elements Ques 27

27. For two ionic solids $CaO$ and $KI$, identify the wrong statement amongst the following : [1997]

(a) The lattice energy of $CaO$ is much large than that of KI

(b) $KI$ is more soluble in water

(c) KI has higher melting point

(d) $CaO$ has higher melting point

Show Answer

Solution:

  1. (c) $CaO$ has higher lattice energy because of higher charge on $Ca^{2+}$ and $O^{2-}$, which results in higher attraction. $KI$ is more soluble in water because of low lattice energy and higher hydration energy. Clearly (c) is wrong because $CaO$ has higher melting point as compared to KI.


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