The Sblock Elements Ques 31

31. Sodium is made by the electrolysis of a molten mixture of about $40 \% NaCl$ and $60 \% CaCl_2$ because

[1995]

(a) $Ca^{2+}$ can reduce $NaCl$ to $Na$

(b) $Ca^{2+}$ can displace $Na$ from $NaCl$

(c) $CaCl_2$ helps in conduction of electricity

(d) this mixture has a lower melting point than $NaCl$

Show Answer

Solution:

  1. (d) Sodium is obtained by electrolytic reduction of its chloride. Melting point of chloride of sodium is high $(803^{\circ} C)$ so in order to lower its melting point $(600^{\circ} C)$, calcium chloride is added to it.


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