Kinetic Theory Ques 18

18. A gas mixture consists of $2$ moles of $O_2$ and $4$ moles of $Ar$ at temperature $T$. Neglecting all vibrational modes, the total internal energy of the system is :-

[2017]

(a) $15 $ $RT$

(b) $9 $ $RT$

(c) $11 $ $RT$

(d) $4 $ $RT$

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Answer:

Correct Answer: 18.(c)

Solution:

  1. (c) Internal energy of the system is given by

$U=\frac{f}{2} $ $nRT$

Degree of freedom

$F _{\text{diatomic }}=5$

$f _{\text{monoatomic }}=3$

and, number of moles

$n(O_2)=2$

$n(Ar)=4$

$U _{\text{total }}=\frac{5}{2}(2) RT+\frac{3}{2}(4) RT=11$ $ RT$