UNIT III: Electrochemistry
- specific and molar conductivity
- variations of conductivity with concentration
- electrolysis and laws of electrolysis (elementary idea)
- standard electrode potential
- Nernst equation and its application to chemical cells
UNIT IV: Chemical Kinetics
- order and molecularity of a reaction
- integrated rate equations and half-life (only for zero and first-order reactions)
- concept of collision theory (elementary idea, no mathematical treatment)
UNIT V: Surface Chemistry
- Adsorption - physisorption and chemisorption
- factors affecting adsorption of gases on solids
- catalysis - homogeneous and heterogeneous
- activity and selectivity of solid catalysts
- enzyme catalysis and its mechanism
- colloidal state - distinction between true solutions
- multi-molecular and macromolecular colloids
UNIT VI: General Principles and Processes of Isolation of Elements
- Principles and methods of extraction - concentration
- reduction - electrolytic method and refining; occurrence and principles of extraction of aluminium
UNIT VII: P-block Elements
- Group 15 elements: General introduction
- trends in physical and chemical properties; preparation and properties of ammonia and nitric acid
- oxides of nitrogen (structure only)
- Phosphorus - allotropic forms
- compounds of phosphorus - preparation and properties of phosphine
- halides (PCL3, PCL5) and oxoacids (elementary idea only)
UNIT VIII: d and f Block Elements
- characteristics of transition metals
- general trends in properties of the first-row transition metals - metallic character
UNIT IX: Coordination Compounds
- Coordination compounds - introduction
- magnetic properties and shapes
- bonding - Werner’s theory
- importance of coordination compounds (in qualitative analysis, biological systems)
UNIT X: Haloalkanes and Haloarenes
- physical and chemical properties
- mechanism of substitution reactions
- substitution reactions (directive influence of halogen in monosubstituted compounds only)
UNIT XI: Alcohols, Phenols, and Ethers
- physical and chemical properties (of primary alcohols only)
- identification of primary
- secondary and tertiary alcohols
- uses with special reference to methanol and ethanol
- physical and chemical properties
- electrophilic substitution reactions
- physical and chemical properties
UNIT XII: Aldehydes, Ketones, and Carboxylic Acids
- Aldehydes and Ketones: Nomenclature
- physical and chemical properties
- mechanism of nucleophilic addition
- reactivity of alpha hydrogen in aldehydes and uses
- Carboxylic Acids: Nomenclature
- physical and chemical properties; uses
UNIT XIII: Organic Compounds Containing Nitrogen
- physical and chemical properties, uses
- identification of primary
- secondary and tertiary amines
- Cyanides and Isocyanides: Nomenclature
- physical and chemical properties, uses
- and importance in synthetic organic chemistry
UNIT XVI: Chemistry in Everyday Life
- Chemicals in medicines: Analgesics
- Chemicals in food: Preservatives
- artificial sweetening agents
- elementary idea of antioxidants
- Cleansing agents: Soaps and detergents