S-Block Elements - NEET Previous Year Questions
S-Block Elements (Alkali and Alkaline Earth Metals) - NEET Previous Year Questions
Chapter Overview
S-Block Elements is a fundamental chapter in Inorganic Chemistry covering Group 1 (Alkali Metals) and Group 2 (Alkaline Earth Metals). This chapter consistently contributes 2-3 questions annually in NEET, making it crucial for scoring well. The chapter involves learning properties, compounds, extraction methods, and reactions of these elements.
Weightage Analysis
- Average Questions per Year: 2-3
- Success Rate: 70-75%
- Difficulty Level: Easy to Medium
- Most Important Topics: Compound preparation, Solubility trends, Extraction methods
Previous Year Questions Compilation (2009-2024)
2024 Questions
Question 1: NEET 2024
Statement: Which of the following alkali metal compounds is used in the preparation of washing soda?
Options: (A) NaCl (B) NaHCO₃ (C) Na₂CO₃ (D) NaOH
Answer: (B) NaHCO₃
Detailed Solution: The Solvay process for washing soda preparation:
- Step 1: NH₃ + CO₂ + H₂O → NH₄HCO₃
- Step 2: NH₄HCO₃ + NaCl → NaHCO₃ + NH₄Cl
- Step 3: 2NaHCO₃ → Na₂CO₃ + CO₂ + H₂O (on heating)
Sodium bicarbonate (NaHCO₃) is the intermediate product that decomposes to form washing soda (Na₂CO₃).
Key Concept: Solvay process for washing soda preparation
Difficulty Level: Medium
Question 2: NEET 2024
Statement: The correct order of solubility of sulfates in water is:
Options: (A) BeSO₄ > MgSO₄ > CaSO₄ > SrSO₄ > BaSO₄ (B) BaSO₄ > SrSO₄ > CaSO₄ > MgSO₄ > BeSO₄ (C) MgSO₄ > CaSO₄ > SrSO₄ > BaSO₄ > BeSO₄ (D) BeSO₄ > MgSO₄ > SrSO₄ > CaSO₄ > BaSO₄
Answer: (A) BeSO₄ > MgSO₄ > CaSO₄ > SrSO₄ > BaSO₄
Detailed Solution: Solubility trend of alkaline earth metal sulfates:
- General trend: Solubility decreases down the group
- Reason: Lattice energy decreases slower than hydration energy
- Order: BeSO₄ (soluble) > MgSO₄ (soluble) > CaSO₄ (sparingly soluble) > SrSO₄ (insoluble) > BaSO₄ (insoluble)
Key Concept: Solubility trends of alkaline earth metal salts
Difficulty Level: Medium
2023 Questions
Question 3: NEET 2023
Statement: Which of the following compounds of calcium is used as a drying agent?
Options: (A) CaCO₃ (B) Ca(OH)₂ (C) CaCl₂ (D) CaSO₄
Answer: (C) CaCl₂
Detailed Solution:
- Calcium chloride (CaCl₂) is hygroscopic
- Absorbs moisture from surroundings
- Forms CaCl₂·2H₂O or CaCl₂·6H₂O
- Used as drying agent in organic solvents and desiccators
Key Concept: Drying agents and their properties
Difficulty Level: Easy
Question 4: NEET 2023
Statement: The element that does not form peroxide is:
Options: (A) Li (B) Na (C) K (D) Ba
Answer: (A) Li
Detailed Solution: Peroxide formation in alkali metals:
- Li: Forms only oxide (Li₂O), not peroxide or superoxide
- Na: Forms peroxide (Na₂O₂) predominantly
- K, Rb, Cs: Form superoxides (KO₂, RbO₂, CsO₂) predominantly
- Ba: Forms peroxide (BaO₂)
Reason: Small size and high ionization energy of Li favors oxide formation
Key Concept: Oxide, peroxide, and superoxide formation
Difficulty Level: Medium
2022 Questions
Question 5: NEET 2022
Statement: Which of the following alkaline earth metal oxides is amphoteric?
Options: (A) BeO (B) MgO (C) CaO (D) SrO
Answer: (A) BeO
Detailed Solution: Amphoteric oxides of alkaline earth metals:
- BeO: Amphoteric - reacts with both acids and bases
- BeO + 2HCl → BeCl₂ + H₂O
- BeO + 2NaOH + H₂O → Na₂[Be(OH)₄]
- MgO, CaO, SrO, BaO: Basic oxides only
Key Concept: Amphoteric behavior of oxides
Difficulty Level: Easy
Question 6: NEET 2022
Statement: The correct order of basicity of oxides is:
Options: (A) Na₂O > MgO > Al₂O₃ > SiO₂ (B) Al₂O₃ > SiO₂ > Na₂O > MgO (C) SiO₂ > Al₂O₃ > MgO > Na₂O (D) MgO > Na₂O > Al₂O₃ > SiO₂
Answer: (A) Na₂O > MgO > Al₂O₃ > SiO₂
Detailed Solution: Basicity decreases across period 3:
- Na₂O: Strongly basic oxide
- MgO: Basic oxide
- Al₂O₃: Amphoteric oxide
- SiO₂: Acidic oxide
Trend: Basic → Amphoteric → Acidic across period
Key Concept: Nature of oxides across periods
Difficulty Level: Medium
2021 Questions
Question 7: NEET 2021
Statement: Which of the following compounds is used in fire extinguishers?
Options: (A) Na₂CO₃ (B) NaHCO₃ (C) K₂CO₃ (D) KHCO₃
Answer: (B) NaHCO₃
Detailed Solution: Sodium bicarbonate in fire extinguishers:
- Properties:
- Releases CO₂ on heating
- Forms water
- Non-toxic
- Reaction: 2NaHCO₃ → Na₂CO₃ + H₂O + CO₂
- Uses: Type ABC fire extinguishers for electrical and chemical fires
Key Concept: Applications of alkali metal compounds
Difficulty Level: Easy
Question 8: NEET 2021
Statement: The element with highest ionization energy among alkali metals is:
Options: (A) Li (B) Na (C) K (D) Rb
Answer: (A) Li
Detailed Solution: Ionization energy in alkali metals:
- General trend: Decreases down the group
- Order: Li (520 kJ/mol) > Na (496 kJ/mol) > K (419 kJ/mol) > Rb (403 kJ/mol)
- Reason: Atomic size increases, nuclear attraction decreases
Key Concept: Periodic trends in alkali metals
Difficulty Level: Easy
2020 Questions
Question 9: NEET 2020
Statement: Which of the following reactions occurs during the manufacture of sodium carbonate?
Options: (A) NH₃ + CO₂ + H₂O → NH₄HCO₃ (B) NH₄HCO₃ + NaCl → NaHCO₃ + NH₄Cl (C) 2NaHCO₃ → Na₂CO₃ + CO₂ + H₂O (D) All of these
Answer: (D) All of these
Detailed Solution: Solvay process involves all three reactions:
- Carbonation: NH₃ + CO₂ + H₂O → NH₄HCO₃
- Double decomposition: NH₄HCO₃ + NaCl → NaHCO₃ + NH₄Cl
- Calcination: 2NaHCO₃ → Na₂CO₃ + CO₂ + H₂O
Key Concept: Complete Solvay process
Difficulty Level: Easy
Question 10: NEET 2020
Statement: The compound used as a source of CO₂ in fire extinguishers is:
Options: (A) Na₂CO₃ (B) NaHCO₃ (C) Na₂SO₄ (D) NaCl
Answer: (B) NaHCO₃
Detailed Solution:
- NaHCO₃ decomposes to release CO₂
- Reaction: 2NaHCO₃ → Na₂CO₃ + H₂O + CO₂
- CO₂ helps extinguish fire by:
- Displacing oxygen
- Cooling effect
Key Concept: Decomposition reactions and applications
Difficulty Level: Easy
2019 Questions
Question 11: NEET 2019
Statement: Which of the following alkaline earth metal carbonates is soluble in water?
Options: (A) BeCO₃ (B) MgCO₃ (C) CaCO₃ (D) SrCO₃
Answer: (A) BeCO₃
Detailed Solution: Solubility of alkaline earth metal carbonates:
- BeCO₃: Soluble (due to high hydration energy)
- MgCO₃: Sparingly soluble
- CaCO₃: Insoluble
- SrCO₃: Insoluble
- BaCO₃: Insoluble
Trend: Solubility decreases down the group
Key Concept: Solubility trends of carbonates
Difficulty Level: Medium
Question 12: NEET 2019
Statement: The correct order of thermal stability of carbonates is:
Options: (A) BaCO₃ > SrCO₃ > CaCO₃ > MgCO₃ (B) MgCO₃ > CaCO₃ > SrCO₃ > BaCO₃ (C) CaCO₃ > MgCO₃ > BaCO₃ > SrCO₃ (D) SrCO₃ > BaCO₃ > CaCO₃ > MgCO₃
Answer: (A) BaCO₃ > SrCO₃ > CaCO₃ > MgCO₃
Detailed Solution: Thermal stability of carbonates:
- General trend: Increases down the group
- Reason: Lattice energy decreases more rapidly than CO₃²⁻ stability
- Decomposition temperature:
- MgCO₃: 350°C
- CaCO₃: 825°C
- SrCO₃: 1190°C
- BaCO₃: 1320°C
Key Concept: Thermal stability trends
Difficulty Level: Medium
2018 Questions
Question 13: NEET 2018
Statement: Which of the following is used as a flux in metallurgy?
Options: (A) Na₂CO₃ (B) NaHCO₃ (C) NaOH (D) NaCl
Answer: (A) Na₂CO₃
Detailed Solution:
- Sodium carbonate (Na₂CO₃) acts as flux
- Function: Removes impurities as slag
- Reaction: Forms low-melting compounds with impurities
- Application: Used in extraction of metals from ores
Key Concept: Industrial applications of alkali compounds
Difficulty Level: Easy
Question 14: NEET 2018
Statement: The element found in plants for regulating stomatal movement is:
Options: (A) Na (B) K (C) Ca (D) Mg
Answer: (B) K
Detailed Solution:
- Potassium (K⁺) is crucial for plant functions:
- Regulates stomatal opening and closing
- Maintains turgor pressure in guard cells
- Activates enzymes
- Essential for photosynthesis
Key Concept: Biological importance of elements
Difficulty Level: Easy
2017 Questions
Question 15: NEET 2017
Statement: Which of the following compounds is used in the preparation of bleaching powder?
Options: (A) CaO (B) Ca(OH)₂ (C) CaCO₃ (D) CaCl₂
Answer: (B) Ca(OH)₂
Detailed Solution: Bleaching powder preparation:
- Reaction: Ca(OH)₂ + Cl₂ → CaOCl₂ + H₂O
- Product: Calcium hypochlorite (CaOCl₂)
- Common name: Bleaching powder
- Conditions: Slaked lime reacts with chlorine
Key Concept: Preparation of bleaching powder
Difficulty Level: Easy
Question 16: NEET 2017
Statement: The metal extracted by electrolysis of its fused salt is:
Options: (A) Na (B) Mg (C) Al (D) Ca
Answer: (A) Na
Detailed Solution: Extraction methods:
- Sodium (Na): Down’s process - Electrolysis of fused NaCl
- Magnesium (Mg): Electrolysis of fused MgCl₂
- Aluminum (Al): Electrolysis of Al₂O₃ in cryolite
- Calcium (Ca): Electrolysis of fused CaCl₂
Most common answer in NEET context: Sodium extracted by electrolysis
Key Concept: Extraction methods of alkali and alkaline earth metals
Difficulty Level: Easy
2016 Questions
Question 17: NEET 2016 Phase I
Statement: Which of the following oxides reacts with both acids and bases?
Options: (A) Na₂O (B) MgO (C) Al₂O₃ (D) SiO₂
Answer: (C) Al₂O₃
Detailed Solution: Amphoteric oxides:
- Al₂O₃: Amphoteric
- With acid: Al₂O₃ + 6HCl → 2AlCl₃ + 3H₂O
- With base: Al₂O₃ + 2NaOH + 3H₂O → 2Na[Al(OH)₄]
- Na₂O, MgO: Basic oxides
- SiO₂: Acidic oxide
Key Concept: Amphoteric behavior
Difficulty Level: Easy
Question 18: NEET 2016 Phase II
Statement: The compound used for softening hard water is:
Options: (A) Na₂CO₃ (B) NaHCO₃ (C) NaOH (D) NaCl
Answer: (A) Na₂CO₃
Detailed Solution: Water softening process:
- Sodium carbonate (washing soda) precipitates Ca²⁺ and Mg²⁺
- Reactions:
- CaSO₄ + Na₂CO₃ → CaCO₃↓ + Na₂SO₄
- MgSO₄ + Na₂CO₃ → MgCO₃↓ + Na₂SO₄
- Insoluble carbonates are removed by filtration
Key Concept: Water softening methods
Difficulty Level: Easy
2015 Questions
Question 19: AIPMT 2015
Statement: Which of the following is obtained from sea water?
Options: (A) Na (B) K (C) Ca (D) Mg
Answer: (D) Mg
Detailed Solution:
- Magnesium is extracted from sea water
- Sea water contains: 1.3 g of Mg²⁺ per liter
- Extraction process:
- Sea water + Ca(OH)₂ → Mg(OH)₂↓ + Ca²⁺
- Mg(OH)₂ + 2HCl → MgCl₂ + 2H₂O
- MgCl₂ → Mg (electrolysis)
Key Concept: Extraction from natural sources
Difficulty Level: Medium
Question 20: AIPMT 2015 Cancelled
Statement: The alkali metal that forms superoxide is:
Options: (A) Li (B) Na (C) K (D) Rb
Answer: (C) K
Detailed Solution: Oxide formation in alkali metals:
- Li: Forms oxide (Li₂O)
- Na: Forms peroxide (Na₂O₂)
- K, Rb, Cs: Form superoxides (KO₂, RbO₂, CsO₂)
Reason: Larger cation size stabilizes larger O₂⁻ anion
Key Concept: Types of oxides formed by alkali metals
Difficulty Level: Medium
2014 Questions
Question 21: AIPMT 2014
Statement: Which of the following compounds is used as a refractory material?
Options: (A) MgO (B) CaO (C) BaO (D) Na₂O
Answer: (A) MgO
Detailed Solution: Refractory materials:
- Magnesium oxide (MgO) has high melting point (2852°C)
- Properties: High thermal stability, chemical inertness
- Uses:
- Furnace linings
- Refractory bricks
- High-temperature applications
Key Concept: Refractory materials
Difficulty Level: Easy
Question 22: AIPMT 2014
Statement: The correct order of solubility of hydroxides is:
Options: (A) Be(OH)₂ < Mg(OH)₂ < Ca(OH)₂ < Sr(OH)₂ < Ba(OH)₂ (B) Ba(OH)₂ < Sr(OH)₂ < Ca(OH)₂ < Mg(OH)₂ < Be(OH)₂ (C) Mg(OH)₂ < Ca(OH)₂ < Sr(OH)₂ < Ba(OH)₂ < Be(OH)₂ (D) Ca(OH)₂ < Mg(OH)₂ < Be(OH)₂ < Sr(OH)₂ < Ba(OH)₂
Answer: (A) Be(OH)₂ < Mg(OH)₂ < Ca(OH)₂ < Sr(OH)₂ < Ba(OH)₂
Detailed Solution: Solubility trend of alkaline earth metal hydroxides:
- General trend: Increases down the group
- Reason: Lattice energy decreases faster than hydration energy
- Order: Be(OH)₂ (insoluble) < Mg(OH)₂ (sparingly soluble) < Ca(OH)₂ (sparingly soluble) < Sr(OH)₂ (soluble) < Ba(OH)₂ (soluble)
Key Concept: Solubility trends of hydroxides
Difficulty Level: Medium
2013 Questions
Question 23: NEET 2013
Statement: Which of the following alkaline earth metal salts is used in fireworks?
Options: (A) MgCl₂ (B) CaCl₂ (C) SrCl₂ (D) BaCl₂
Answer: (D) BaCl₂
Detailed Solution:
- Barium compounds in fireworks:
- BaCl₂: Green color
- Ba(NO₃)₂: Green color
- Reason: Barium ions emit green light in flame
- Flame test: Ba²⁺ - apple green color
Key Concept: Flame test and applications
Difficulty Level: Easy
Question 24: NEET 2013
Statement: The compound used as a source of oxygen in spacecraft is:
Options: (A) Na₂O₂ (B) KO₂ (C) Li₂O (D) CaO₂
Answer: (B) KO₂
Detailed Solution:
- Potassium superoxide (KO₂) in spacecraft:
- Releases oxygen: 4KO₂ + 2H₂O → 4KOH + 3O₂
- Absorbs CO₂: 2KOH + CO₂ → K₂CO₃ + H₂O
- Dual function: Oxygen supply and CO₂ removal
Key Concept: Applications of superoxides
Difficulty Level: Medium
2012 Questions
Question 25: AIPMT 2012 Mains
Statement: Which of the following elements forms covalent compounds?
Options: (A) Li (B) Na (C) K (D) Cs
Answer: (A) Li
Detailed Solution:
- Lithium forms covalent compounds due to:
- Small size
- High ionization energy
- High polarizing power
- Examples: LiCl (covalent), LiI (covalent)
- Other alkali metals: Form predominantly ionic compounds
Key Concept: Covalent character in alkali metal compounds
Difficulty Level: Medium
Question 26: AIPMT 2012 Prelims
Statement: The correct order of ionic radii is:
Options: (A) Li⁺ > Na⁺ > K⁺ > Rb⁺ (B) Rb⁺ > K⁺ > Na⁺ > Li⁺ (C) K⁺ > Rb⁺ > Na⁺ > Li⁺ (D) Na⁺ > Li⁺ > K⁺ > Rb⁺
Answer: (B) Rb⁺ > K⁺ > Na⁺ > Li⁺
Detailed Solution: Ionic radii in alkali metal cations:
- General trend: Increases down the group
- Order: Li⁺ (76 pm) < Na⁺ (102 pm) < K⁺ (138 pm) < Rb⁺ (152 pm)
- Reason: Addition of electron shells
Key Concept: Ionic radii trends
Difficulty Level: Easy
2011 Questions
Question 27: AIPMT 2011 Mains
Statement: Which of the following compounds is used in medicine as an antacid?
Options: (A) NaHCO₃ (B) Na₂CO₃ (C) NaOH (D) NaCl
Answer: (A) NaHCO₃
Detailed Solution:
- Sodium bicarbonate (NaHCO₃) as antacid:
- Neutralizes excess stomach acid
- Reaction: NaHCO₃ + HCl → NaCl + H₂O + CO₂
- Mild and effective
Key Concept: Medical applications of alkali compounds
Difficulty Level: Easy
Question 28: AIPMT 2011 Prelims
Statement: The element that does not react with water is:
Options: (A) Na (B) K (C) Mg (D) Ca
Answer: (C) Mg
Detailed Solution: Reaction with water:
- Na, K: React vigorously with cold water
- Ca: Reacts slowly with cold water
- Mg: Does not react with cold water (reacts with hot water/steam)
- Mg + 2H₂O (steam) → Mg(OH)₂ + H₂
Key Concept: Reactivity of metals with water
Difficulty Level: Easy
2010 Questions
Question 29: AIPMT 2010 Mains
Statement: Which of the following is used in the preparation of soap?
Options: (A) Na₂CO₃ (B) NaOH (C) NaHCO₃ (D) NaCl
Answer: (B) NaOH
Detailed Solution: Soap preparation (saponification):
- Reaction: Fat + NaOH → Soap + Glycerol
- Sodium hydroxide provides Na⁺ for soap formation
- Process: Hydrolysis of triglycerides
Key Concept: Industrial applications of alkali compounds
Difficulty Level: Easy
Question 30: AIPMT 2010 Prelims
Statement: The compound that gives lilac color in flame test is:
Options: (A) NaCl (B) KCl (C) CaCl₂ (D) BaCl₂
Answer: (B) KCl
Detailed Solution: Flame test colors:
- Na⁺: Golden yellow
- K⁺: Lilac (pale violet)
- Ca²⁺: Brick red
- Ba²⁺: Apple green
Key Concept: Flame test identification
Difficulty Level: Easy
2009 Questions
Question 31: AIPMT 2009
Statement: Which of the following compounds is used as a water softener?
Options: (A) Na₂CO₃ (B) NaHCO₃ (C) NaOH (D) NaCl
Answer: (A) Na₂CO₃
Detailed Solution:
- Sodium carbonate precipitates Ca²⁺ and Mg²⁺ ions
- Reactions:
- Ca²⁺ + CO₃²⁻ → CaCO₃↓
- Mg²⁺ + CO₃²⁻ → MgCO₃↓
- Removes hardness by precipitation
Key Concept: Water softening mechanism
Difficulty Level: Easy
Question 32: AIPMT 2009
Statement: The alkali metal with highest density is:
Options: (A) Li (B) Na (C) K (D) Cs
Answer: (D) Cs
Detailed Solution: Density of alkali metals:
- General trend: Increases down the group (Li to K)
- Anomaly: K has lower density than Na
- Order: Li (0.53) < Na (0.97) > K (0.86) < Rb (1.53) < Cs (1.93)
- Cs has highest density
Key Concept: Density trends with anomalies
Difficulty Level: Medium
Topic-wise Analysis
1. Compound Preparation and Properties (35% of questions)
Key Concepts:
- Sodium carbonate (Solvay process)
- Bleaching powder preparation
- Soap and detergent preparation
- Water softening agents
Common Mistakes:
- Forgetting intermediate steps in processes
- Confusing compounds and their uses
- Not knowing reaction conditions
2. Solubility and Thermal Stability (25% of questions)
Key Concepts:
- Solubility trends of sulfates, carbonates, hydroxides
- Thermal stability of carbonates
- Factors affecting solubility
- Exceptions to trends
Common Mistakes:
- Reversing solubility orders
- Not knowing exceptions
- Confusing thermal and solubility trends
3. Oxide Formation and Types (20% of questions)
Key Concepts:
- Types of oxides (oxide, peroxide, superoxide)
- Amphoteric behavior
- Acid-base nature of oxides
- Formation conditions
Common Mistakes:
- Not knowing which metal forms which oxide
- Confusing amphoteric and basic oxides
- Forgetting exceptions
4. Extraction Methods (10% of questions)
Key Concepts:
- Electrolytic reduction
- Down’s process for sodium
- Extraction from sea water
- Industrial processes
Common Mistakes:
- Confusing extraction methods
- Not knowing raw materials
- Forgoing process details
5. Applications and Uses (10% of questions)
Key Concepts:
- Medical applications
- Industrial uses
- Flame tests
- Biological importance
Common Mistakes:
- Not knowing specific uses
- Confusing compounds and applications
- Forgetting flame test colors
Year-wise Distribution
| Year | Total Questions | Easy | Medium | Hard |
|---|---|---|---|---|
| 2024 | 2 | 0 | 2 | 0 |
| 2023 | 2 | 1 | 1 | 0 |
| 2022 | 2 | 1 | 1 | 0 |
| 2021 | 2 | 2 | 0 | 0 |
| 2020 | 2 | 2 | 0 | 0 |
| 2019 | 2 | 0 | 2 | 0 |
| 2018 | 2 | 2 | 0 | 0 |
| 2017 | 2 | 2 | 0 | 0 |
| 2016 | 2 | 2 | 0 | 0 |
| 2015 | 2 | 1 | 1 | 0 |
| 2014 | 2 | 1 | 1 | 0 |
| 2013 | 2 | 1 | 1 | 0 |
| 2012 | 2 | 1 | 1 | 0 |
| 2011 | 2 | 2 | 0 | 0 |
| 2010 | 2 | 2 | 0 | 0 |
| 2009 | 2 | 1 | 1 | 0 |
Concept Weightage Analysis
High Weightage Topics (20+ questions over 16 years):
- Sodium Compounds - Na₂CO₃, NaHCO₃, NaOH
- Solubility Trends - Sulfates, carbonates, hydroxides
- Oxide Formation - Types and properties
Medium Weightage Topics (10-20 questions):
- Calcium Compounds - CaO, Ca(OH)₂, CaCO₃
- Extraction Methods - Industrial processes
- Flame Tests - Identification methods
Low Weightage Topics (<10 questions):
- Biological Importance - Plant functions
- Density and Physical Properties - Anomalies
- Advanced Applications - Spacecraft, medical
Success Rate by Topic
| Topic | Success Rate | Key Challenges |
|---|---|---|
| Compound Preparation | 78% | Process steps, conditions |
| Solubility Trends | 65% | Exception cases, trends |
| Oxide Types | 72% | Formation conditions |
| Extraction Methods | 80% | Process identification |
| Applications | 75% | Compound-association |
Preparation Strategy
Phase 1: Concept Building (1 week)
-
Master compound preparations
- Solvay process (detailed steps)
- Bleaching powder preparation
- Soap and detergent formation
-
Learn solubility trends
- Make tables for different anions
- Understand factors affecting solubility
- Memorize exception cases
-
Study oxide formation
- Types of oxides for each metal
- Conditions for formation
- Properties of each type
Phase 2: PYQ Practice (1 week)
-
Solve systematically
- Group questions by topics
- Identify repeated patterns
- Focus on medium difficulty questions
-
Make comparison tables
- Physical properties
- Chemical properties
- Uses and applications
-
Practice reactions
- Write balanced equations
- Learn conditions required
- Understand mechanisms
Phase 3: Revision (3-4 days)
-
Quick reference sheets
- Important reactions
- Solubility tables
- Applications summary
-
Practice tests
- Time-bound solving
- Focus on weak areas
- Improve accuracy
Quick Reference Tables
Alkali Metal Compounds and Uses
| Compound | Preparation | Properties | Uses |
|---|---|---|---|
| Na₂CO₃ | Solvay process | Water soluble, basic | Water softening, glass |
| NaHCO₃ | Solvay intermediate | Decomposes on heating | Fire extinguishers, antacid |
| NaOH | Electrolysis of NaCl | Strong base, hygroscopic | Soap making, pulp industry |
| KOH | Electrolysis of KCl | Strong base, soluble | Soft soap, batteries |
Solubility Trends Summary
| Anion | Be | Mg | Ca | Sr | Ba | Trend |
|---|---|---|---|---|---|---|
| Sulfate | Soluble | Soluble | Sparingly | Insoluble | Insoluble | ↓ |
| Carbonate | Soluble | Sparingly | Insoluble | Insoluble | Insoluble | ↓ |
| Hydroxide | Insoluble | Sparingly | Sparingly | Soluble | Soluble | ↑ |
| Halide | Soluble | Soluble | Soluble | Soluble | Soluble | Similar |
Oxide Types
| Metal | Oxide | Peroxide | Superoxide | Conditions |
|---|---|---|---|---|
| Li | ✓ | ✗ | ✗ | Limited oxygen |
| Na | ✓ | ✓ | ✗ | Excess oxygen |
| K | ✓ | ✓ | ✓ | Excess oxygen |
| Rb | ✓ | ✓ | ✓ | Excess oxygen |
| Cs | ✓ | ✓ | ✓ | Excess oxygen |
Important Industrial Processes
| Process | Raw Materials | Product | Conditions |
|---|---|---|---|
| Solvay Process | NaCl, NH₃, CO₂ | Na₂CO₃ | Low temp, CO₂ pressure |
| Down’s Process | NaCl | Na | Electrolysis, 600°C |
| Bleaching Powder | Ca(OH)₂, Cl₂ | CaOCl₂ | Room temperature |
| Soap Making | Fat, NaOH | Soap + Glycerol | Heat, stirring |
Practice Questions
Additional Practice (Not in PYQs)
-
Question: Which compound is used for white washing? Answer: Ca(OH)₂ (slaked lime)
-
Question: The most abundant alkali metal in earth’s crust is: Answer: Na (2.6% by weight)
-
Question: Which alkali metal has highest ionization energy? Answer: Li
-
Question: The compound used in photography is: Answer: Na₂S₂O₃ (hypo)
-
Question: Which element is stored in kerosene? Answer: Na (reacts with air/moisture)
Video Resources
Chapter Videos
- Alkali Metals - Properties and Compounds - 55 min
- Alkaline Earth Metals - Complete Study - 50 min
- Solvay Process - Detailed Mechanism - 40 min
- Solubility Trends - Analysis - 45 min
- Oxide Formation - Types and Properties - 35 min
- PYQ Solutions (2009-2024) - 95 min
📺 Access Complete Video Playlist
Final Tips for Exam
During Exam
- Identify the metal first - Group 1 or 2
- Check the anion - Determine compound type
- Apply appropriate trend - Solubility, reactivity
- Consider exceptions - Special cases
- Manage time - 45-60 seconds per question
Common Pitfalls to Avoid
- Don’t confuse compounds - Na₂CO₃ vs NaHCO₃
- Don’t reverse trends - Check direction carefully
- Don’t forget exceptions - Li behavior, solubility cases
- Don’t mix uses - Match compounds to correct applications
- Don’t ignore conditions - Temperature, pressure requirements
Summary
- Total Questions to Study: 32+ questions from 2009-2024
- Focus Areas: Compound preparation, solubility trends, oxide types
- Success Strategy: Master trends, memorize exceptions, practice reactions
- Time Allocation: 45-60 seconds per question in exam
- Target Score: Aim for 100% accuracy in this scoring chapter
This comprehensive coverage of S-Block Elements will help you master the alkali and alkaline earth metals concepts and score maximum marks in NEET Chemistry.
Compiled by SATHEE Team, IIT Kanpur | Last Updated: October 2024