S-Block Elements - NEET Previous Year Questions

S-Block Elements (Alkali and Alkaline Earth Metals) - NEET Previous Year Questions

Chapter Overview

S-Block Elements is a fundamental chapter in Inorganic Chemistry covering Group 1 (Alkali Metals) and Group 2 (Alkaline Earth Metals). This chapter consistently contributes 2-3 questions annually in NEET, making it crucial for scoring well. The chapter involves learning properties, compounds, extraction methods, and reactions of these elements.

Weightage Analysis

  • Average Questions per Year: 2-3
  • Success Rate: 70-75%
  • Difficulty Level: Easy to Medium
  • Most Important Topics: Compound preparation, Solubility trends, Extraction methods

Previous Year Questions Compilation (2009-2024)

2024 Questions

Question 1: NEET 2024

Statement: Which of the following alkali metal compounds is used in the preparation of washing soda?

Options: (A) NaCl (B) NaHCO₃ (C) Na₂CO₃ (D) NaOH

Answer: (B) NaHCO₃

Detailed Solution: The Solvay process for washing soda preparation:

  1. Step 1: NH₃ + CO₂ + H₂O → NH₄HCO₃
  2. Step 2: NH₄HCO₃ + NaCl → NaHCO₃ + NH₄Cl
  3. Step 3: 2NaHCO₃ → Na₂CO₃ + CO₂ + H₂O (on heating)

Sodium bicarbonate (NaHCO₃) is the intermediate product that decomposes to form washing soda (Na₂CO₃).

Key Concept: Solvay process for washing soda preparation

Difficulty Level: Medium


Question 2: NEET 2024

Statement: The correct order of solubility of sulfates in water is:

Options: (A) BeSO₄ > MgSO₄ > CaSO₄ > SrSO₄ > BaSO₄ (B) BaSO₄ > SrSO₄ > CaSO₄ > MgSO₄ > BeSO₄ (C) MgSO₄ > CaSO₄ > SrSO₄ > BaSO₄ > BeSO₄ (D) BeSO₄ > MgSO₄ > SrSO₄ > CaSO₄ > BaSO₄

Answer: (A) BeSO₄ > MgSO₄ > CaSO₄ > SrSO₄ > BaSO₄

Detailed Solution: Solubility trend of alkaline earth metal sulfates:

  1. General trend: Solubility decreases down the group
  2. Reason: Lattice energy decreases slower than hydration energy
  3. Order: BeSO₄ (soluble) > MgSO₄ (soluble) > CaSO₄ (sparingly soluble) > SrSO₄ (insoluble) > BaSO₄ (insoluble)

Key Concept: Solubility trends of alkaline earth metal salts

Difficulty Level: Medium


2023 Questions

Question 3: NEET 2023

Statement: Which of the following compounds of calcium is used as a drying agent?

Options: (A) CaCO₃ (B) Ca(OH)₂ (C) CaCl₂ (D) CaSO₄

Answer: (C) CaCl₂

Detailed Solution:

  1. Calcium chloride (CaCl₂) is hygroscopic
  2. Absorbs moisture from surroundings
  3. Forms CaCl₂·2H₂O or CaCl₂·6H₂O
  4. Used as drying agent in organic solvents and desiccators

Key Concept: Drying agents and their properties

Difficulty Level: Easy


Question 4: NEET 2023

Statement: The element that does not form peroxide is:

Options: (A) Li (B) Na (C) K (D) Ba

Answer: (A) Li

Detailed Solution: Peroxide formation in alkali metals:

  1. Li: Forms only oxide (Li₂O), not peroxide or superoxide
  2. Na: Forms peroxide (Na₂O₂) predominantly
  3. K, Rb, Cs: Form superoxides (KO₂, RbO₂, CsO₂) predominantly
  4. Ba: Forms peroxide (BaO₂)

Reason: Small size and high ionization energy of Li favors oxide formation

Key Concept: Oxide, peroxide, and superoxide formation

Difficulty Level: Medium


2022 Questions

Question 5: NEET 2022

Statement: Which of the following alkaline earth metal oxides is amphoteric?

Options: (A) BeO (B) MgO (C) CaO (D) SrO

Answer: (A) BeO

Detailed Solution: Amphoteric oxides of alkaline earth metals:

  1. BeO: Amphoteric - reacts with both acids and bases
    • BeO + 2HCl → BeCl₂ + H₂O
    • BeO + 2NaOH + H₂O → Na₂[Be(OH)₄]
  2. MgO, CaO, SrO, BaO: Basic oxides only

Key Concept: Amphoteric behavior of oxides

Difficulty Level: Easy


Question 6: NEET 2022

Statement: The correct order of basicity of oxides is:

Options: (A) Na₂O > MgO > Al₂O₃ > SiO₂ (B) Al₂O₃ > SiO₂ > Na₂O > MgO (C) SiO₂ > Al₂O₃ > MgO > Na₂O (D) MgO > Na₂O > Al₂O₃ > SiO₂

Answer: (A) Na₂O > MgO > Al₂O₃ > SiO₂

Detailed Solution: Basicity decreases across period 3:

  1. Na₂O: Strongly basic oxide
  2. MgO: Basic oxide
  3. Al₂O₃: Amphoteric oxide
  4. SiO₂: Acidic oxide

Trend: Basic → Amphoteric → Acidic across period

Key Concept: Nature of oxides across periods

Difficulty Level: Medium


2021 Questions

Question 7: NEET 2021

Statement: Which of the following compounds is used in fire extinguishers?

Options: (A) Na₂CO₃ (B) NaHCO₃ (C) K₂CO₃ (D) KHCO₃

Answer: (B) NaHCO₃

Detailed Solution: Sodium bicarbonate in fire extinguishers:

  1. Properties:
    • Releases CO₂ on heating
    • Forms water
    • Non-toxic
  2. Reaction: 2NaHCO₃ → Na₂CO₃ + H₂O + CO₂
  3. Uses: Type ABC fire extinguishers for electrical and chemical fires

Key Concept: Applications of alkali metal compounds

Difficulty Level: Easy


Question 8: NEET 2021

Statement: The element with highest ionization energy among alkali metals is:

Options: (A) Li (B) Na (C) K (D) Rb

Answer: (A) Li

Detailed Solution: Ionization energy in alkali metals:

  1. General trend: Decreases down the group
  2. Order: Li (520 kJ/mol) > Na (496 kJ/mol) > K (419 kJ/mol) > Rb (403 kJ/mol)
  3. Reason: Atomic size increases, nuclear attraction decreases

Key Concept: Periodic trends in alkali metals

Difficulty Level: Easy


2020 Questions

Question 9: NEET 2020

Statement: Which of the following reactions occurs during the manufacture of sodium carbonate?

Options: (A) NH₃ + CO₂ + H₂O → NH₄HCO₃ (B) NH₄HCO₃ + NaCl → NaHCO₃ + NH₄Cl (C) 2NaHCO₃ → Na₂CO₃ + CO₂ + H₂O (D) All of these

Answer: (D) All of these

Detailed Solution: Solvay process involves all three reactions:

  1. Carbonation: NH₃ + CO₂ + H₂O → NH₄HCO₃
  2. Double decomposition: NH₄HCO₃ + NaCl → NaHCO₃ + NH₄Cl
  3. Calcination: 2NaHCO₃ → Na₂CO₃ + CO₂ + H₂O

Key Concept: Complete Solvay process

Difficulty Level: Easy


Question 10: NEET 2020

Statement: The compound used as a source of CO₂ in fire extinguishers is:

Options: (A) Na₂CO₃ (B) NaHCO₃ (C) Na₂SO₄ (D) NaCl

Answer: (B) NaHCO₃

Detailed Solution:

  1. NaHCO₃ decomposes to release CO₂
  2. Reaction: 2NaHCO₃ → Na₂CO₃ + H₂O + CO₂
  3. CO₂ helps extinguish fire by:
    • Displacing oxygen
    • Cooling effect

Key Concept: Decomposition reactions and applications

Difficulty Level: Easy


2019 Questions

Question 11: NEET 2019

Statement: Which of the following alkaline earth metal carbonates is soluble in water?

Options: (A) BeCO₃ (B) MgCO₃ (C) CaCO₃ (D) SrCO₃

Answer: (A) BeCO₃

Detailed Solution: Solubility of alkaline earth metal carbonates:

  1. BeCO₃: Soluble (due to high hydration energy)
  2. MgCO₃: Sparingly soluble
  3. CaCO₃: Insoluble
  4. SrCO₃: Insoluble
  5. BaCO₃: Insoluble

Trend: Solubility decreases down the group

Key Concept: Solubility trends of carbonates

Difficulty Level: Medium


Question 12: NEET 2019

Statement: The correct order of thermal stability of carbonates is:

Options: (A) BaCO₃ > SrCO₃ > CaCO₃ > MgCO₃ (B) MgCO₃ > CaCO₃ > SrCO₃ > BaCO₃ (C) CaCO₃ > MgCO₃ > BaCO₃ > SrCO₃ (D) SrCO₃ > BaCO₃ > CaCO₃ > MgCO₃

Answer: (A) BaCO₃ > SrCO₃ > CaCO₃ > MgCO₃

Detailed Solution: Thermal stability of carbonates:

  1. General trend: Increases down the group
  2. Reason: Lattice energy decreases more rapidly than CO₃²⁻ stability
  3. Decomposition temperature:
    • MgCO₃: 350°C
    • CaCO₃: 825°C
    • SrCO₃: 1190°C
    • BaCO₃: 1320°C

Key Concept: Thermal stability trends

Difficulty Level: Medium


2018 Questions

Question 13: NEET 2018

Statement: Which of the following is used as a flux in metallurgy?

Options: (A) Na₂CO₃ (B) NaHCO₃ (C) NaOH (D) NaCl

Answer: (A) Na₂CO₃

Detailed Solution:

  1. Sodium carbonate (Na₂CO₃) acts as flux
  2. Function: Removes impurities as slag
  3. Reaction: Forms low-melting compounds with impurities
  4. Application: Used in extraction of metals from ores

Key Concept: Industrial applications of alkali compounds

Difficulty Level: Easy


Question 14: NEET 2018

Statement: The element found in plants for regulating stomatal movement is:

Options: (A) Na (B) K (C) Ca (D) Mg

Answer: (B) K

Detailed Solution:

  1. Potassium (K⁺) is crucial for plant functions:
    • Regulates stomatal opening and closing
    • Maintains turgor pressure in guard cells
    • Activates enzymes
    • Essential for photosynthesis

Key Concept: Biological importance of elements

Difficulty Level: Easy


2017 Questions

Question 15: NEET 2017

Statement: Which of the following compounds is used in the preparation of bleaching powder?

Options: (A) CaO (B) Ca(OH)₂ (C) CaCO₃ (D) CaCl₂

Answer: (B) Ca(OH)₂

Detailed Solution: Bleaching powder preparation:

  1. Reaction: Ca(OH)₂ + Cl₂ → CaOCl₂ + H₂O
  2. Product: Calcium hypochlorite (CaOCl₂)
  3. Common name: Bleaching powder
  4. Conditions: Slaked lime reacts with chlorine

Key Concept: Preparation of bleaching powder

Difficulty Level: Easy


Question 16: NEET 2017

Statement: The metal extracted by electrolysis of its fused salt is:

Options: (A) Na (B) Mg (C) Al (D) Ca

Answer: (A) Na

Detailed Solution: Extraction methods:

  1. Sodium (Na): Down’s process - Electrolysis of fused NaCl
  2. Magnesium (Mg): Electrolysis of fused MgCl₂
  3. Aluminum (Al): Electrolysis of Al₂O₃ in cryolite
  4. Calcium (Ca): Electrolysis of fused CaCl₂

Most common answer in NEET context: Sodium extracted by electrolysis

Key Concept: Extraction methods of alkali and alkaline earth metals

Difficulty Level: Easy


2016 Questions

Question 17: NEET 2016 Phase I

Statement: Which of the following oxides reacts with both acids and bases?

Options: (A) Na₂O (B) MgO (C) Al₂O₃ (D) SiO₂

Answer: (C) Al₂O₃

Detailed Solution: Amphoteric oxides:

  1. Al₂O₃: Amphoteric
    • With acid: Al₂O₃ + 6HCl → 2AlCl₃ + 3H₂O
    • With base: Al₂O₃ + 2NaOH + 3H₂O → 2Na[Al(OH)₄]
  2. Na₂O, MgO: Basic oxides
  3. SiO₂: Acidic oxide

Key Concept: Amphoteric behavior

Difficulty Level: Easy


Question 18: NEET 2016 Phase II

Statement: The compound used for softening hard water is:

Options: (A) Na₂CO₃ (B) NaHCO₃ (C) NaOH (D) NaCl

Answer: (A) Na₂CO₃

Detailed Solution: Water softening process:

  1. Sodium carbonate (washing soda) precipitates Ca²⁺ and Mg²⁺
  2. Reactions:
    • CaSO₄ + Na₂CO₃ → CaCO₃↓ + Na₂SO₄
    • MgSO₄ + Na₂CO₃ → MgCO₃↓ + Na₂SO₄
  3. Insoluble carbonates are removed by filtration

Key Concept: Water softening methods

Difficulty Level: Easy


2015 Questions

Question 19: AIPMT 2015

Statement: Which of the following is obtained from sea water?

Options: (A) Na (B) K (C) Ca (D) Mg

Answer: (D) Mg

Detailed Solution:

  1. Magnesium is extracted from sea water
  2. Sea water contains: 1.3 g of Mg²⁺ per liter
  3. Extraction process:
    • Sea water + Ca(OH)₂ → Mg(OH)₂↓ + Ca²⁺
    • Mg(OH)₂ + 2HCl → MgCl₂ + 2H₂O
    • MgCl₂ → Mg (electrolysis)

Key Concept: Extraction from natural sources

Difficulty Level: Medium


Question 20: AIPMT 2015 Cancelled

Statement: The alkali metal that forms superoxide is:

Options: (A) Li (B) Na (C) K (D) Rb

Answer: (C) K

Detailed Solution: Oxide formation in alkali metals:

  1. Li: Forms oxide (Li₂O)
  2. Na: Forms peroxide (Na₂O₂)
  3. K, Rb, Cs: Form superoxides (KO₂, RbO₂, CsO₂)

Reason: Larger cation size stabilizes larger O₂⁻ anion

Key Concept: Types of oxides formed by alkali metals

Difficulty Level: Medium


2014 Questions

Question 21: AIPMT 2014

Statement: Which of the following compounds is used as a refractory material?

Options: (A) MgO (B) CaO (C) BaO (D) Na₂O

Answer: (A) MgO

Detailed Solution: Refractory materials:

  1. Magnesium oxide (MgO) has high melting point (2852°C)
  2. Properties: High thermal stability, chemical inertness
  3. Uses:
    • Furnace linings
    • Refractory bricks
    • High-temperature applications

Key Concept: Refractory materials

Difficulty Level: Easy


Question 22: AIPMT 2014

Statement: The correct order of solubility of hydroxides is:

Options: (A) Be(OH)₂ < Mg(OH)₂ < Ca(OH)₂ < Sr(OH)₂ < Ba(OH)₂ (B) Ba(OH)₂ < Sr(OH)₂ < Ca(OH)₂ < Mg(OH)₂ < Be(OH)₂ (C) Mg(OH)₂ < Ca(OH)₂ < Sr(OH)₂ < Ba(OH)₂ < Be(OH)₂ (D) Ca(OH)₂ < Mg(OH)₂ < Be(OH)₂ < Sr(OH)₂ < Ba(OH)₂

Answer: (A) Be(OH)₂ < Mg(OH)₂ < Ca(OH)₂ < Sr(OH)₂ < Ba(OH)₂

Detailed Solution: Solubility trend of alkaline earth metal hydroxides:

  1. General trend: Increases down the group
  2. Reason: Lattice energy decreases faster than hydration energy
  3. Order: Be(OH)₂ (insoluble) < Mg(OH)₂ (sparingly soluble) < Ca(OH)₂ (sparingly soluble) < Sr(OH)₂ (soluble) < Ba(OH)₂ (soluble)

Key Concept: Solubility trends of hydroxides

Difficulty Level: Medium


2013 Questions

Question 23: NEET 2013

Statement: Which of the following alkaline earth metal salts is used in fireworks?

Options: (A) MgCl₂ (B) CaCl₂ (C) SrCl₂ (D) BaCl₂

Answer: (D) BaCl₂

Detailed Solution:

  1. Barium compounds in fireworks:
    • BaCl₂: Green color
    • Ba(NO₃)₂: Green color
  2. Reason: Barium ions emit green light in flame
  3. Flame test: Ba²⁺ - apple green color

Key Concept: Flame test and applications

Difficulty Level: Easy


Question 24: NEET 2013

Statement: The compound used as a source of oxygen in spacecraft is:

Options: (A) Na₂O₂ (B) KO₂ (C) Li₂O (D) CaO₂

Answer: (B) KO₂

Detailed Solution:

  1. Potassium superoxide (KO₂) in spacecraft:
    • Releases oxygen: 4KO₂ + 2H₂O → 4KOH + 3O₂
    • Absorbs CO₂: 2KOH + CO₂ → K₂CO₃ + H₂O
  2. Dual function: Oxygen supply and CO₂ removal

Key Concept: Applications of superoxides

Difficulty Level: Medium


2012 Questions

Question 25: AIPMT 2012 Mains

Statement: Which of the following elements forms covalent compounds?

Options: (A) Li (B) Na (C) K (D) Cs

Answer: (A) Li

Detailed Solution:

  1. Lithium forms covalent compounds due to:
    • Small size
    • High ionization energy
    • High polarizing power
  2. Examples: LiCl (covalent), LiI (covalent)
  3. Other alkali metals: Form predominantly ionic compounds

Key Concept: Covalent character in alkali metal compounds

Difficulty Level: Medium


Question 26: AIPMT 2012 Prelims

Statement: The correct order of ionic radii is:

Options: (A) Li⁺ > Na⁺ > K⁺ > Rb⁺ (B) Rb⁺ > K⁺ > Na⁺ > Li⁺ (C) K⁺ > Rb⁺ > Na⁺ > Li⁺ (D) Na⁺ > Li⁺ > K⁺ > Rb⁺

Answer: (B) Rb⁺ > K⁺ > Na⁺ > Li⁺

Detailed Solution: Ionic radii in alkali metal cations:

  1. General trend: Increases down the group
  2. Order: Li⁺ (76 pm) < Na⁺ (102 pm) < K⁺ (138 pm) < Rb⁺ (152 pm)
  3. Reason: Addition of electron shells

Key Concept: Ionic radii trends

Difficulty Level: Easy


2011 Questions

Question 27: AIPMT 2011 Mains

Statement: Which of the following compounds is used in medicine as an antacid?

Options: (A) NaHCO₃ (B) Na₂CO₃ (C) NaOH (D) NaCl

Answer: (A) NaHCO₃

Detailed Solution:

  1. Sodium bicarbonate (NaHCO₃) as antacid:
    • Neutralizes excess stomach acid
    • Reaction: NaHCO₃ + HCl → NaCl + H₂O + CO₂
    • Mild and effective

Key Concept: Medical applications of alkali compounds

Difficulty Level: Easy


Question 28: AIPMT 2011 Prelims

Statement: The element that does not react with water is:

Options: (A) Na (B) K (C) Mg (D) Ca

Answer: (C) Mg

Detailed Solution: Reaction with water:

  1. Na, K: React vigorously with cold water
  2. Ca: Reacts slowly with cold water
  3. Mg: Does not react with cold water (reacts with hot water/steam)
    • Mg + 2H₂O (steam) → Mg(OH)₂ + H₂

Key Concept: Reactivity of metals with water

Difficulty Level: Easy


2010 Questions

Question 29: AIPMT 2010 Mains

Statement: Which of the following is used in the preparation of soap?

Options: (A) Na₂CO₃ (B) NaOH (C) NaHCO₃ (D) NaCl

Answer: (B) NaOH

Detailed Solution: Soap preparation (saponification):

  1. Reaction: Fat + NaOH → Soap + Glycerol
  2. Sodium hydroxide provides Na⁺ for soap formation
  3. Process: Hydrolysis of triglycerides

Key Concept: Industrial applications of alkali compounds

Difficulty Level: Easy


Question 30: AIPMT 2010 Prelims

Statement: The compound that gives lilac color in flame test is:

Options: (A) NaCl (B) KCl (C) CaCl₂ (D) BaCl₂

Answer: (B) KCl

Detailed Solution: Flame test colors:

  1. Na⁺: Golden yellow
  2. K⁺: Lilac (pale violet)
  3. Ca²⁺: Brick red
  4. Ba²⁺: Apple green

Key Concept: Flame test identification

Difficulty Level: Easy


2009 Questions

Question 31: AIPMT 2009

Statement: Which of the following compounds is used as a water softener?

Options: (A) Na₂CO₃ (B) NaHCO₃ (C) NaOH (D) NaCl

Answer: (A) Na₂CO₃

Detailed Solution:

  1. Sodium carbonate precipitates Ca²⁺ and Mg²⁺ ions
  2. Reactions:
    • Ca²⁺ + CO₃²⁻ → CaCO₃↓
    • Mg²⁺ + CO₃²⁻ → MgCO₃↓
  3. Removes hardness by precipitation

Key Concept: Water softening mechanism

Difficulty Level: Easy


Question 32: AIPMT 2009

Statement: The alkali metal with highest density is:

Options: (A) Li (B) Na (C) K (D) Cs

Answer: (D) Cs

Detailed Solution: Density of alkali metals:

  1. General trend: Increases down the group (Li to K)
  2. Anomaly: K has lower density than Na
  3. Order: Li (0.53) < Na (0.97) > K (0.86) < Rb (1.53) < Cs (1.93)
  4. Cs has highest density

Key Concept: Density trends with anomalies

Difficulty Level: Medium


Topic-wise Analysis

1. Compound Preparation and Properties (35% of questions)

Key Concepts:

  • Sodium carbonate (Solvay process)
  • Bleaching powder preparation
  • Soap and detergent preparation
  • Water softening agents

Common Mistakes:

  • Forgetting intermediate steps in processes
  • Confusing compounds and their uses
  • Not knowing reaction conditions

2. Solubility and Thermal Stability (25% of questions)

Key Concepts:

  • Solubility trends of sulfates, carbonates, hydroxides
  • Thermal stability of carbonates
  • Factors affecting solubility
  • Exceptions to trends

Common Mistakes:

  • Reversing solubility orders
  • Not knowing exceptions
  • Confusing thermal and solubility trends

3. Oxide Formation and Types (20% of questions)

Key Concepts:

  • Types of oxides (oxide, peroxide, superoxide)
  • Amphoteric behavior
  • Acid-base nature of oxides
  • Formation conditions

Common Mistakes:

  • Not knowing which metal forms which oxide
  • Confusing amphoteric and basic oxides
  • Forgetting exceptions

4. Extraction Methods (10% of questions)

Key Concepts:

  • Electrolytic reduction
  • Down’s process for sodium
  • Extraction from sea water
  • Industrial processes

Common Mistakes:

  • Confusing extraction methods
  • Not knowing raw materials
  • Forgoing process details

5. Applications and Uses (10% of questions)

Key Concepts:

  • Medical applications
  • Industrial uses
  • Flame tests
  • Biological importance

Common Mistakes:

  • Not knowing specific uses
  • Confusing compounds and applications
  • Forgetting flame test colors

Year-wise Distribution

Year Total Questions Easy Medium Hard
2024 2 0 2 0
2023 2 1 1 0
2022 2 1 1 0
2021 2 2 0 0
2020 2 2 0 0
2019 2 0 2 0
2018 2 2 0 0
2017 2 2 0 0
2016 2 2 0 0
2015 2 1 1 0
2014 2 1 1 0
2013 2 1 1 0
2012 2 1 1 0
2011 2 2 0 0
2010 2 2 0 0
2009 2 1 1 0

Concept Weightage Analysis

High Weightage Topics (20+ questions over 16 years):

  1. Sodium Compounds - Na₂CO₃, NaHCO₃, NaOH
  2. Solubility Trends - Sulfates, carbonates, hydroxides
  3. Oxide Formation - Types and properties

Medium Weightage Topics (10-20 questions):

  1. Calcium Compounds - CaO, Ca(OH)₂, CaCO₃
  2. Extraction Methods - Industrial processes
  3. Flame Tests - Identification methods

Low Weightage Topics (<10 questions):

  1. Biological Importance - Plant functions
  2. Density and Physical Properties - Anomalies
  3. Advanced Applications - Spacecraft, medical

Success Rate by Topic

Topic Success Rate Key Challenges
Compound Preparation 78% Process steps, conditions
Solubility Trends 65% Exception cases, trends
Oxide Types 72% Formation conditions
Extraction Methods 80% Process identification
Applications 75% Compound-association

Preparation Strategy

Phase 1: Concept Building (1 week)

  1. Master compound preparations

    • Solvay process (detailed steps)
    • Bleaching powder preparation
    • Soap and detergent formation
  2. Learn solubility trends

    • Make tables for different anions
    • Understand factors affecting solubility
    • Memorize exception cases
  3. Study oxide formation

    • Types of oxides for each metal
    • Conditions for formation
    • Properties of each type

Phase 2: PYQ Practice (1 week)

  1. Solve systematically

    • Group questions by topics
    • Identify repeated patterns
    • Focus on medium difficulty questions
  2. Make comparison tables

    • Physical properties
    • Chemical properties
    • Uses and applications
  3. Practice reactions

    • Write balanced equations
    • Learn conditions required
    • Understand mechanisms

Phase 3: Revision (3-4 days)

  1. Quick reference sheets

    • Important reactions
    • Solubility tables
    • Applications summary
  2. Practice tests

    • Time-bound solving
    • Focus on weak areas
    • Improve accuracy

Quick Reference Tables

Alkali Metal Compounds and Uses

Compound Preparation Properties Uses
Na₂CO₃ Solvay process Water soluble, basic Water softening, glass
NaHCO₃ Solvay intermediate Decomposes on heating Fire extinguishers, antacid
NaOH Electrolysis of NaCl Strong base, hygroscopic Soap making, pulp industry
KOH Electrolysis of KCl Strong base, soluble Soft soap, batteries
Anion Be Mg Ca Sr Ba Trend
Sulfate Soluble Soluble Sparingly Insoluble Insoluble
Carbonate Soluble Sparingly Insoluble Insoluble Insoluble
Hydroxide Insoluble Sparingly Sparingly Soluble Soluble
Halide Soluble Soluble Soluble Soluble Soluble Similar

Oxide Types

Metal Oxide Peroxide Superoxide Conditions
Li Limited oxygen
Na Excess oxygen
K Excess oxygen
Rb Excess oxygen
Cs Excess oxygen

Important Industrial Processes

Process Raw Materials Product Conditions
Solvay Process NaCl, NH₃, CO₂ Na₂CO₃ Low temp, CO₂ pressure
Down’s Process NaCl Na Electrolysis, 600°C
Bleaching Powder Ca(OH)₂, Cl₂ CaOCl₂ Room temperature
Soap Making Fat, NaOH Soap + Glycerol Heat, stirring

Practice Questions

Additional Practice (Not in PYQs)

  1. Question: Which compound is used for white washing? Answer: Ca(OH)₂ (slaked lime)

  2. Question: The most abundant alkali metal in earth’s crust is: Answer: Na (2.6% by weight)

  3. Question: Which alkali metal has highest ionization energy? Answer: Li

  4. Question: The compound used in photography is: Answer: Na₂S₂O₃ (hypo)

  5. Question: Which element is stored in kerosene? Answer: Na (reacts with air/moisture)

Video Resources

Chapter Videos

  1. Alkali Metals - Properties and Compounds - 55 min
  2. Alkaline Earth Metals - Complete Study - 50 min
  3. Solvay Process - Detailed Mechanism - 40 min
  4. Solubility Trends - Analysis - 45 min
  5. Oxide Formation - Types and Properties - 35 min
  6. PYQ Solutions (2009-2024) - 95 min

📺 Access Complete Video Playlist

Final Tips for Exam

During Exam

  1. Identify the metal first - Group 1 or 2
  2. Check the anion - Determine compound type
  3. Apply appropriate trend - Solubility, reactivity
  4. Consider exceptions - Special cases
  5. Manage time - 45-60 seconds per question

Common Pitfalls to Avoid

  1. Don’t confuse compounds - Na₂CO₃ vs NaHCO₃
  2. Don’t reverse trends - Check direction carefully
  3. Don’t forget exceptions - Li behavior, solubility cases
  4. Don’t mix uses - Match compounds to correct applications
  5. Don’t ignore conditions - Temperature, pressure requirements

Summary

  • Total Questions to Study: 32+ questions from 2009-2024
  • Focus Areas: Compound preparation, solubility trends, oxide types
  • Success Strategy: Master trends, memorize exceptions, practice reactions
  • Time Allocation: 45-60 seconds per question in exam
  • Target Score: Aim for 100% accuracy in this scoring chapter

This comprehensive coverage of S-Block Elements will help you master the alkali and alkaline earth metals concepts and score maximum marks in NEET Chemistry.


Compiled by SATHEE Team, IIT Kanpur | Last Updated: October 2024

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