Alcohols and Ethers - Result Question 45

50. Give reasons for the following in one or two sentences. “Acid catalysed dehydration of $t$-butanol is faster than that of $n$-butanol.

$(1998,2 M)$

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Solution:

  1. Acid catalysed dehydration proceeds via carbocation intermediate. Also, greater the stability of reactive intermediate, faster the reaction :

<img src=“https://temp-public-img-folder.s3.amazonaws.com/sathee.prutor.images/sathee_image/cropped_2024_01_16_b4fdca9f34924034e8d8g-362_jpg_height_213_width_580_top_left_y_1096_top_left_x_290.jpg"width="350">

$n$-butanol forms less stable $\left(1^{\circ}\right)$ carbocation.



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