Coordination Compounds 1 Question 20

Assertion and Reason

Read the following questions and answer as per the direction given below :

(a) Statement I is true; Statement II is true; Statement II is the correct explanation of Statement I.

(b) Statement I is true; Statement II is true; Statement II is not the correct explanation of Statement I.

(c) Statement I is true; Statement II is false.

(d) Statement I is false; Statement II is true.

20.

Statement I The geometrical isomers of the complex $\left[M\left(NH _3\right) _4 Cl _2\right]$ are optically inactive.

Statement II Both geometrical isomers of the complex $\left[M\left(NH _3\right) _4 Cl _2\right]$ possess axis of symmetry.

$(2008,3 M)$

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Answer:

Correct Answer: 20. (b)

Solution:

  1. Both statements are true. However, axis of symmetry is not a criteria of optical isomerism. Optical inactivity of the two geometrical isomers of $\left[M\left(NH _3\right) _4 Cl _2\right]$ is due to the presence of plane of symmetry.

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