Hydrocarbons - Result Question 47

30. Which one of the following has the smallest heat of hydrogenation per mole?

(1993,1 M)

(a) $1$-butene

(b) trans-$2$-butene

(c) cis-$2$-butene

(d) $1, 3$-butadiene

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Answer:

Correct Answer: 30. (b)

Solution:

  1. Among alkenes-heat of hydrogenation depends on :

(a) The number of double bonds-greater, greater the amount of heat evolved in hydrogenation.

Hence, $1, 3$-butadiene has highest heat of hydrogenation among these.

(b) Relative stability of alkenes-greater the stability, smaller the heat evolved in hydrogenation. trans-$2$-butene is most stable among three given butenes, has least heat of hydrogenation.