Hydrocarbons - Result Question 50

34. When propyne is treated with aqueous $H _2 SO _4$ in the presence of $HgSO _4$, the major product is

(1983,1 M)

(a) propanal

(b) propyl hydrogen sulphate

(c) acetone

(d) propanol

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Answer:

Correct Answer: 34. $(c)$

Solution:

  1. Alkynes undergo Markownikoff’s addition of water in the presence of $H _2 SO _4 / HgSO _4$ :