Hydrocarbons - Result Question 62

Passage

Schemes $1$ and $2$ describe sequential transformation of alkynes M and N. Consider only the major products formed in each step for both schemes.

47. The product $X$ is

<img src=“https://temp-public-img-folder.s3.amazonaws.com/sathee.prutor.images/sathee_image/snip_images_J3hjyIzPYg1bJT7GueO6DLU0u5VTpbHSi9temUHxLZI_original_fullsize_png.jpg" width =“400 px” / >

Show Answer

Answer:

Correct Answer: 47. (a)

Solution:

  1. PLAN: This problem can be solved by using the concept of nucleophilic substitution reaction, oxidation reaction and reduction reaction including strength of nucleophile and regioselectivity.

Reaction of Scheme 1 can be completed as

<img src=“https://temp-public-img-folder.s3.amazonaws.com/sathee.prutor.images/sathee_image/cropped_2024_01_16_b4fdca9f34924034e8d8g-334_jpg_height_132_width_723_top_left_y_1992_top_left_x_290.jpg" width =“400 px” / >

Among two naked nucleophilic group I and II, II is more nucleophilic and then will react selectively as follows

<img src=“https://temp-public-img-folder.s3.amazonaws.com/sathee.prutor.images/sathee_image/cropped_2024_01_16_b4fdca9f34924034e8d8g-334_jpg_height_422_width_761_top_left_y_2197_top_left_x_274.jpg" width =“400 px” / >

Hence, using the concept of regioselectivity, we come to the conclusion that the final product is correctly represented by structure (a).



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