Hydrocarbons - Result Question 8

8. Benzyl chloride $\left(C _6 H _5 CH _2 Cl\right)$ can be prepared from toluene by chlorination with

(1998)

(a) $SO _2 Cl _2$

(b) $SOCl _2$

(c) $Cl _2$

(d) $NaOCl$

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Answer:

Correct Answer: 8. (c)

Solution:

  1. Toluene on treatment with $Cl _2$ in the presence of heat or light undergo free-radical chlorination at benzylic position, giving benzyl chloride

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