Organic Chemistry Basics - Result Question 106

Assertion and Reason

Read the following questions and answer as per the direction given below:

(a) Statement I is correct; Statement II is correct; Statement II is the correct explanation of Statement I

(b) Statement I is correct; Statement II is correct; Statement II is not the correct explanation of Statement I

(c) Statement I is correct; Statement II is incorrect

(d) Statement I is incorrect; Statement II is correct

58.

Statement I $p$-hydroxybenzoic acid has a lower boiling point than $o$-hydroxybenzoic acid.

Statement II $o$-hydroxybenzoic acid has intramolecular hydrogen bonding.

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Answer:

Correct Answer: 58. (d)

Solution:

  1. Statement I is incorrect; Statement II is correct. Intramolecular H-bonding in ortho-hydroxy benzoic acid lowers the boiling point.


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