Organic Chemistry Basics - Result Question 130

82. Give reasons for the following in one or two sentences. The central carbon-carbon bond in 1, 3-butadiene is shorter than that of $n$-butane.

(1998)

Show Answer

Solution:


<img src=“https://temp-public-img-folder.s3.amazonaws.com/sathee.prutor.images/sathee_image/cropped_2024_01_16_b4fdca9f34924034e8d8g-320_jpg_height_121_width_700_top_left_y_585_top_left_x_310.jpg"width="410">

The above shown resonance introduces some double bond character to central $C-C$ bond. Therefore, the central $C-C$ bond in 1, 3-butadiene is shorter (stronger) than $C-C$ bond in butane.