Organic Chemistry Basics Result Question 31

Arrange in order of increasing acidic strength

(a) $X>Z>Y$

(b) $Z< X >Y$

(c) $X>Y>Z$

(d) $Z>X>Y$

$(2004,1 M)$

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Answer:

Correct Answer: 31. ( a )

Solution:

  1. Carboxylic acid is stronger acid than ammonium ion, hence $-\mathrm{COOH}(X)$ is most acidic. $\mathrm{Z}\left(\stackrel{+}{\mathrm{N}} \mathrm{H} _3\right)$ is more acidic than $Y\left(\stackrel{+}{\mathrm{N}} \mathrm{H} _3\right)$ due to $-I$ effect of $-\mathrm{COOH}$ on $Z$. Hence, overall acid strength order is

$ \quad X>Z>Y $



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