Organic Chemistry Basics Result Question 9

9. If dichloromethane (DCM) and water $\left(\mathrm{H} _2 \mathrm{O}\right)$ are used for differential extraction, which one of the following statements is correct?

(a) DCM and $\mathrm{H} _2 \mathrm{O}$ would stay as lower and upper layer respectively in the S.F.

(b) DCM and $\mathrm{H} _2 \mathrm{O}$ would stay as upper and lower layer respectively in the separating funnel (S.F.)

(c) DCM and $\mathrm{H} _2 \mathrm{O}$ will be miscible clearly

(d) DCM and $\mathrm{H} _2 \mathrm{O}$ will make turbid/colloidal mixture

(2019 Main, 10 Jan I)

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Answer:

Correct Answer: 9. ( a )

Solution:

  1. Dichloromethane, DCM $\left(\mathrm{CH}_2 \mathrm{Cl}_2\right)$ is heavier (density $=1.3266 \mathrm{~g} \mathrm{~cm}^{-3}$ ) than water $\left(\right.$ density $\left.=1 \mathrm{~g} \mathrm{~cm}^{-3}\right)$. So, DCM and $\mathrm{H}_2 \mathrm{O}$ will stay as lower and upper layer respectively in the separating funnel (SF).