sblock Elements 2 Question 14

14. The oxidation state of the most electronegative element in the products of the reaction, $\mathrm{BaO}_2$ with dil. $\mathrm{H}_2 \mathrm{SO}_4$ are

(1991, 1M)

(a) 0 and -1

(b) -1 and -2

(c) -2 and 0

(d) -2 and -1

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Answer:

Correct Answer: 14. (d)

Solution: The reaction involved is

$ \mathrm{BaO}_2+\mathrm{H}_2 \mathrm{SO}_4 \longrightarrow \mathrm{BaSO}_4+\mathrm{H}_2 \mathrm{O}_2 $

The most electronegative atom, oxygen, in $\mathrm{BaSO}_4$ and $\mathrm{H}_2 \mathrm{O}_2$ has -2 and -1 oxidation state respectively.