sblock Elements 2 Question 15

15. Calcium is obtained by

(1980, 1M)

(a) electrolysis of molten $\mathrm{CaCl}_2$

(b) electrolysis of solution of $\mathrm{CaCl}_2$ in water

(c) reduction of $\mathrm{CaCl}_2$ with carbon

(d) roasting of limestone

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Answer:

Correct Answer: 15. (a)

Solution: Electrolysis of molten $\mathrm{CaCl}_2$ gives calcium at cathode

$ \mathrm{Ca}^{2+}+2 e^{-} \longrightarrow \mathrm{Ca} \quad \text { (at cathode) } $

In case of electrolysis in aqueous medium, less electropositive $\mathrm{H}^{+}$is reduced at cathode rather than $\mathrm{Ca}^{2+}$.



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