sblock Elements - Result Question 32

42. Highly pure dilute solution of sodium in liquid ammonia

(a) shows blue colour

(b) exhibits electrical conductivity

(c) produces sodium amide

(d) produces hydrogen gas

$(1998,2 M)$

Show Answer

Answer:

Correct Answer: 42. $(a, b)$

Solution:

  1. In dilute solution of $Na$ in liquid ammonia, solvated electrons are present whose emission spectrum gives blue colouration to solution.

$$ Na+NH _3 \longrightarrow Na^{+}+\underset{\text { Solvated electron }}{NH _3\left(e^{-}\right)} $$

Also, presence of solvated electrons and solvated $Na^{+}$ion makes solution highly conducting.



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