Alkyl Halides - Result Question 28

28. An $S _N 2$ reaction at an asymmetric carbon of a compound always gives

(2001)

(a) an enantiomer of the substrate

(b) a product with opposite optical rotation

(c) a mixture of diastereomers

(d) a single stereoisomer

Show Answer

Answer:

Correct Answer: 28. (d)

Solution:

  1. $S _N 2$ reaction at asymmetric carbon occur with inversion of configuration and a single steroisomer is formed because the reactant and product are not enthtiomer. Therefore the sign of optical rotation may or may not change.


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