Carboxylic Acids and their Derivatives - Result Question 11

11. When propionic acid is treated with aqueous sodium bicarbonate, $CO _2$ is liberated. The $C$ of $CO _2$ comes from

$(1999,2 M)$

(a) methyl group

(b) carboxylic acid group

(c) methylene group

(d) bicarbonate group

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Answer:

Correct Answer: 11. (d)

Solution:

$ CH _3-CH _2-COOH + NaH \stackrel{*}C O _3 \longrightarrow CH _3 CH _2 COONa + H _2 O + \stackrel{*}C O _2 $