Carboxylic Acids and their Derivatives - Result Question 33

Assertion and Reason

Read the following questions and answer as per the direction given below :

(a) Statement I is true; Statement II is true; Statement II is a correct explanation of Statement I.

(b) Statement I is true; Statement II is true; Statement II is not the correct explanation of Statement I.

(c) Statement I is true; Statement II is false.

(d) Statement I is false; Statement II is true

19.

Statement I $p$-hydroxybenzoic acid has a lower boiling point than $o$-hydroxybenzoic acid.

Statement II $o$-hydroxybenzoic acid has intramolecular hydrogen bonding.

(2007, 3M)

Show Answer

Answer:

Correct Answer: 19. (d)

Solution:

$p$-hydroxy benzoic acid has higher boiling point than $o$-hydroxy benzoic acid because former prefers intermolecular $H$-bonding while the latter prefer intramolecular $H$-bonding.

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