Carboxylic Acids and their Derivatives - Result Question 37

Passage

$P$ and $Q$ are isomers of dicarboxylic acid $\mathrm{C}_4 \mathrm{H}_4 \mathrm{O}_4$. Both decolourize $\mathrm{Br}_2 / \mathrm{H}_2 \mathrm{O}$. On heating, $P$ forms the cyclic anhydride. Upon treatment with dilute alkaline $\mathrm{KMnO}_4 \cdot P$ as well as $Q$ could produce one or more than one form $S, T$ and $U$.

(2013 Adv.)

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24. In the following reaction sequences $V$ and $W$ are respectively

$ Q \xrightarrow[\Delta]{H _2 / Ni} V $

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alt text

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Show Answer

Answer:

Correct Answer: 24. (a)

Solution:

PLAN: $Ni/H_2$ reduces $(C = C)$ bond.

Benzene undergoes Friedel - Crafts reaction $Zn-Hg/HCl$ reduces carbonyl group (Clemmmensen reduction)

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