Carboxylic Acids and their Derivatives - Result Question 45

31. The total number of carboxylic acid groups in the product $P$ is

(2013 Adv.)

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Answer:

Correct Answer: 31. $(2)$

Solution:

PLAN: Reactant is cyclic anhydride and changes to dicarboxylic acid on hydrolysis.

Also there is decarboxylation on heating if there is keto group w.r.t $-COOH$ group. Ozonolysis cleaves $(\mathrm{C}=\mathrm{C})$ bond and $\mathrm{H}_2 \mathrm{O}_2$ oxidises $-CHO$ to $-COOH$ group.

<img src=“https://temp-public-img-folder.s3.amazonaws.com/sathee.prutor.images/sathee_image/snip_images_oD6sU95MMUBcKHd_MJzWmb_jGZC7m4I5F40ST7Zbbx4_original_fullsize_png.jpg"width="380"/>

Thus, number of $-COOH$ groups in $P = 2$



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