Chemical And Ionic Equilibrium Result Question 12

12. How many litres of water must be added to $1 \mathrm{~L}$ of an aqueous solution of $\mathrm{HCl}$ with a $\mathrm{pH}$ of $1$ to create an aqueous solution with $\mathrm{pH}$ of $2$ ?

(2013 Main)

(a) $0.1 \mathrm{~L}$

(b) $0.9 \mathrm{~L}$

(c) $2.0 \mathrm{~L}$

(d) $9.0 \mathrm{~L}$

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Answer:

Correct Answer: 12. ( d )

Solution:

$\begin{aligned} \mathrm{pH}=1 \therefore\left[\mathrm{H}^{+}\right] & =10^{-1}=0.1 \mathrm{M} \\ \mathrm{pH} & =2 \therefore\left[\mathrm{H}^{+}\right]=10^{-2}=0.01 \mathrm{M} \end{aligned}$

For dilution of $\mathrm{HCl}, M_1 V_1=M_2 V_2$

$\begin{aligned} 0.1 \times 1 & =0.01 \times V_2 \\ V_2 & =10 \mathrm{~L} \end{aligned}$

Volume of water to be added $=10-1=9 \mathrm{~L}$