Chemical And Ionic Equilibrium Result Question 33

33. Of the given anions, the strongest base is

(1981,1 M)

(a) $\mathrm{ClO}^{-}$

(b) $\mathrm{ClO}_2^{-}$

(c) $\mathrm{ClO}_3^{-}$

(d) $\mathrm{ClO}_4^{-}$

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Answer:

Correct Answer: 33. ( a )

Solution:

  1. The order of acidic strength of conjugate acids is

$ \mathrm{HOCl} < \mathrm{HClO} _2 < \mathrm{HClO} _3 < \mathrm{HClO} _4 $

Reverse is the order of basic strength of their conjugate base, i.e. $\mathrm{ClO}^-$ is the strongest base.