Chemical And Ionic Equilibrium Result Question 37

37. Aqueous solutions of $\mathrm{HNO} _3 ,\mathrm{KOH}, \mathrm{CH} _3 \mathrm{COOH}$ and $\mathrm{CH} _3 \mathrm{COONa}$ of identical concentrations are provided. The pair(s) of solutions which form a buffer upon mixing is(are)

$(2010)$

(a) $\mathrm{HNO} _3$ and $\mathrm{CH} _3 \mathrm{COOH}$

(b) $\mathrm{KOH}$ and $\mathrm{CH} _3 \mathrm{COONa}$

(c) $\mathrm{HNO} _3$ and $\mathrm{CH} _3 \mathrm{COONa}$

(d) $\mathrm{CH} _3 \mathrm{COOH}$ and $\mathrm{CH} _3 \mathrm{COONa}$

Show Answer

Answer:

Correct Answer: 37. ( c,d )

Solution:

  1. In $\mathrm{HNO}_3$ and $\mathrm{CH}_3 \mathrm{COONa}$ combination, if $\mathrm{HNO}_3$ is present in limiting amount, it will be neutralised completely, leaving behind some excess of $\mathrm{CH}_3 \mathrm{COONa}$.