Some Basic Concepts of Chemistry - Result Question 11

12. Consider a titration of potassium dichromate solution with acidified Mohr’s salt solution using diphenylamine as indicator. The number of moles of Mohr’s salt required per mole of dichromate is

(2007, 3M)

(a) 3

(b) 4

(c) 5

(d) 6

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Answer:

Correct Answer: 12. (d)

Solution:

  1. $n$-factor of dichromate is 6 .

Also, $n$-factor of Mohr’s salt is 1 as :

$\because 1$ mole of dichromate $=6$ equivalent of dichromate.

$\therefore 6$ equivalent of Mohr’s salt would be required.

Since, $n$-factor of Mohr’s salt is 1,6 equivalent of it would also be equal to 6 moles.

Hence, 1 mole of dichromate will oxidise 6 moles of Mohr’s salt.