Aryl Halides and Phenols - Result Question 26

29. Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halide due to

$(1990,1 M)$

(a) the formation of less stable carbonium ion

(b) resonance stabilisation

(c) longer carbon halogen bond

(d) $s p^{2}$ -hybridised carbon bonded to halogen

Show Answer

Answer:

Correct Answer: 29. (b, d)

Solution:

Above resonance makes $X$ - a poor leaving group. Also, the carbon bearing $X$ is $s p^{2}$ - hybridised.