Aryl Halides and Phenols - Result Question 27

Assertion and Reason

Read the following questions and answer as per the direction given below :

(a) Statement I is correct; Statement II is correct Statement II is the correct explanation of Statement I

(b) Statement I is correct; Statement II is correct Statement II is not the correct explanation of Statement I

(c) Statement I is correct; Statement II is incorrect

(d) Statement I is incorrect; Statement II is correct

30.

Statement I Bromobenzene, upon reaction with $Br _2 / Fe$ gives $1,4$ -dibromobenzene as the major product.

Statement II In bromobenzene, the inductive effect of the bromo group is more dominant than the mesomeric effect in directing the incoming electrophile.

$(2008,3 M)$

Show Answer

Answer:

Correct Answer: 30. (c)

Solution:

Bromo group is deactivating due to dominance of inductive effect over resonance effect. However, orientation is determined by mesomeric effet of $-Br$.



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