Aryl Halides and Phenols - Result Question 3

4. The organic compound that gives following qualitative analysis is

(2019 Main, 9 April I)

Test Inference
(i) Dil. HCl Insoluble
(ii) NaOH Solution Soluble
(iii) $Br_2$/water Decolourisation
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Answer:

Correct Answer: 4. (b)

Solution:

Phenol $(ArOH)$ is insoluble in dil. $HCl$ and readily soluble in $NaOH$ solution. It reacts with $Br _2$ /water to give $2,4 , 6$ -tribromophenol. It readily decolourises the yellow colour of $Br _2$ water. Reactions involved are as follows :

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