Aryl Halides and Phenols - Result Question 3
4. The organic compound that gives following qualitative analysis is
(2019 Main, 9 April I)
| Test | Inference | ||
|---|---|---|---|
| (i) | Dil. HCl | Insoluble | |
| (ii) | NaOH Solution | Soluble | |
| (iii) | $Br_2$/water | Decolourisation |
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Answer:
Correct Answer: 4. (b)
Solution:
Phenol $(ArOH)$ is insoluble in dil. $HCl$ and readily soluble in $NaOH$ solution. It reacts with $Br _2$ /water to give $2,4 , 6$ -tribromophenol. It readily decolourises the yellow colour of $Br _2$ water. Reactions involved are as follows :